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Background Single-use anaesthetic drug trays are used widely in Australia, but their environmental impact is unclear. Methods A life cycle assessment was completed for 10 different types of single-use anaesthetic drug trays made of four materials: the synthetic plastics polypropylene and polystyrene, and the natural fi...
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Different waste treatment options for municipal solid waste have been studied in a systems analysis. Different combinations of incineration, materials recycling of separated plastic and cardboard containers, and biological treatment (anaerobic digestion and composting) of biodegradable waste, were studied and compared ...
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Naphthenic acids (NAs) are naturally occurring organic acids present in crude oil and bitumen as contaminants. Their presence in the crude oil greatly reduces the quality and price of crude oil. NAs also causes corrosion in the production and processing facilities. They are quantified in the petroleum as Total acid num...
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Material quality, and opportunities for multiple reprocessing, need to be considered when analysing the overall carbon footprint and energy efficiency of plastic products in life cycle assessments. This is rarely done today. This paper presents a case study evaluating a closed-loop recycling system involving a plastics...
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The direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol is a green synthetic route owing to nontoxicity of starting materials and synthetic process. DMC is widely used as a nontoxic solvent, effective fuel additive, and synthetic intermediate in medicine, pharmaceutics, chemistry and other fields. The ke...
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China's express delivery service industry has been experiencing rapid development; in 2021, deliveries reached a total of 108.29 billion. However, with the increasing demand for express packaging and the accompanying environmental pressures, the widespread adoption of returnable mailing packaging has become a key consi...
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Owing to their various advantages, such as low photodamage and high tissue penetration, carbon dots (CDs) with long emission wavelength have gained much attention, and are used to compensate for blue to green fluorescent CDs. However, their synthesis has been challenging. In the present study, an acid-mediated synthesi...
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With the advent of powerful machine learning algorithms strongly supporting complex non-linear regression modeling, catalyst design features for a wide and customized set of catalysts used for a specific reaction have been made easy. Herein, we use these techniques in the methanol synthesis by CO2 reduction over Cu-bas...
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Tea dregs, an abundant and easily found bio-waste, were utilized as a precursor to developing acid biochar (SO3H-TDAC) that was used as a catalyst in producing biodiesel through oleic acid (OA) esterification with methanol. SO3H-TDAC catalysts were prepared through the consecutive carbonization–sulfonation two-step met...
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In-situ (trans)esterification (ISTE) of lipids in post-hydrolyzed rice bran (PHRB) with methanol under subcritical conditions has proven to be a suitable feedstock for fatty acid methyl ester (FAME) production. The lipids from PHRB had a fatty acid profile which was primarily composed of oleic (39 wt%) and linoleic (36...
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Increasing atmospheric pollution with greenhouse gases, a large proportion of which are transport pollutants, is forcing the search for new fuels from renewable sources. Biodiesel is currently produced by transesterification of plant oils over heterogeneous catalysts under gentle conditions. The other recent technology...
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A large portion of plastic produced each year is used to make single-use packaging and other short-lived consumer products that are discarded quickly, creating significant amounts of waste. It is important that such waste be managed appropriately in line with circular-economy principles. One option for managing plastic...
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Synthesis of methanol via CO2 hydrogenation is a very important reaction. In recent years, the In2O3 based catalysts were proved to be a sort of promising catalysts to accelerate this reaction, which have aroused extensive attention. However, design of novel In2O3 based catalysts that can efficiently produce methanol f...
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The cultivation of whole crop forage maize (Zea mays L.) for cattle feed has a potential for increased forage yield while reducing nitrogen (N) fertilisation compared to perennial grass-based systems. However, the possible environmental trade-offs of forage maize cultivation remain unknown in the boreal region due to t...
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Enhancing the sustainability of food packaging (FP) is challenging due to the conflicting environmental and functional requirements, even though it leads to many negative environmental impacts over different life cycle phases. Sustainable FP aims to strike a balance in fulfilling protection, facilitation of handling, a...
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In recent years, a number of new guidelines and frameworks for Life Cycle Assessment (LCA) have emerged, trying to support analysts in dealing with certain methodological issues and “gaps” of the ISO 14040-44, that are still the main LCA reference standards. This trend can be considered as positive, because the lack of...
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Many road construction and maintenance projects are increasingly using recycled material as pavement material. Most of the times, generic sustainability evaluations are ascribed to recycled products without fully considering their performance. The potential environmental benefits of various alternatives can be analytic...
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Recent European regulations have imposed ecological alternatives to the packaging of expanded polystyrene (EPS) dairy products. In this study we explore the opportunity to replace the expanded polystyrene packaging, with a corrugated cardboard coated with bioplastic for the storage and transport of cheese and mozzarell...
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Polyethylene terephthalate (PET) recycling is considered as one of the key approaches to achieving the circular economy (CE) of plastic waste. Bottle-to-Bottle and Bottle-to-Fiber recycling were assessed using Life Cycle Assessment (LCA) and Material Circularity Indicator (MCI). Three allocation methods (i.e., substitu...
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Since long before the use of disposable foil, plastic and paper cups, clay cups have been widely used in India as single-use containers for a variety of beverages and foods. This is now changing. The cost, convenience and transportability of non-earthen containers has resulted in their replacing clay containers. This p...
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By computer simulation, we analyze the performances of a compact (2 meter-long) externally-cooled multitubular reactor for the methanol synthesis loaded with highly conductive structured catalysts, namely washcoated copper honeycomb monoliths and copper open-cell foams. Such a reactor is simulated as inserted in a synt...
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For commercially viable direct methanol fuel cells, electrocatalysts play a crucial role in motivating the sluggish methanol oxidation reaction (MOR) over anode. Unfortunately, the large-scale applications of current MOR catalysts are hampered by their poor tolerance to poisoning and fast activity degradation. Herein, ...
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The feasibility of carrying out the low-pressure methanol-synthesis process in forced unsteady-state conditions, using a network of three catalytic fixed bed reactors with periodical change of the inlet position, has been investigated; advantages and limitations in comparison with the previously proposed reverse-flow r...
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The push to control the greenhouse gas emissions is motivated by environmental regulations. For the aim to be achieved, the suggestion of eliminating or at least reducing gas flaring is currently taken under environment. In this regard, a new configuration for flare gas treatment is proposed in this study. This configu...
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There is a serious need to assess the evolution of transitions from a linear to a Circular Economy (CE) using tools, metrics, and measurement indicators that not only are able to take into account the circularity, but also the other sustainability performances of products. Currently, most measurement tools do not lead ...
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Cu/ZnO-based catalysts are widely used for methanol production from CO/CO2/H2. In recent years there has been growing interest in methanol synthesis from CO2/H2. Cu/ ZnO catalysts are less active for methanol production in CO2-rich feed gas, but the activity appears to be promoted by the addition of Pd to the catalyst....
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Methanol conversion over SAPO molecular sieve DNL-6 was investigated from the view point of the reaction mechanism. The organic materials confined in the cavities of DNL-6 were mostly polymethylbenezenes. By combination of in situ NMR study with ex situ GC–MS measurements, the structure of heptamethylbenzenium ion (hep...
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To address an innovative trigeneration process using coke oven gas as the input fuel, a novel heat integration process based on a solid oxide fuel cell is designed and discussed in the current research. Since the coke oven gas is a hydrogen-enriched fuel, its application in a solid oxide fuel cell power plant can impro...
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The rapid growth of the packaging industry has resulted in a substantial increase in waste and pollution. Regulations, goals and social responsibilities have reoriented businesses’ priorities towards sustainable practices. The life cycle assessment (LCA) carried out in this study measured and compared significant effor...
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This study conducted a full life cycle analysis of bottled water on four types of bottles: ENSO, PLA (corn based), recycled PET, and regular (petroleum based) PET, to discern which bottle material is more beneficial to use in terms of environmental impacts. PET bottles are the conventional bottles used that are not bio...
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This study evaluated the environmental impacts caused by drinking water consumption in Barcelona (Spain) using the Life Cycle Assessment (LCA) methodology. Five different scenarios were compared: 1) tap water from conventional drinking water treatment; 2) tap water from conventional drinking water treatment with revers...
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Ordered bimodal mesoporous boria–alumina composite (OBMBAC) with high specific surface area and pore volume has been prepared through an evaporation-induced self-assembly (EISA) process using non-ionic block copolymer as a template without addition of any mineral acids such as HCl or H2SO4. Nitrogen adsorption test, lo...
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The introduction of reusable packaging systems (both refill and return) has the potential to significantly reduce waste from single-use plastic packaging. However, for these schemes to be successful, both the environmental impact and the willingness of consumers to engage with such systems need to be carefully consider...
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Methanol is rated among the top chemical commodities worldwide. Its production via indirect synthesis routes from natural gas is energy intensive and costly regarding the investment and operation. This study addresses the economics of methanol synthesis routes with different reforming technologies. Processes with steam...
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Coordination complexes and metal–organic frameworks are compounds with unlimited applications in electrochemistry. Those based on Co, Ni, and Cu offer redox-active properties that can be an advantage for the electro-oxidation of short-chain alcohols in alkaline media. At the present, there is a crescent interest for it...
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Bio-based plastics are produced from bio-based raw materials such as sugar cane, potatoes, corn, and agricultural and slaughterhouse waste. The evolution of the bio-based plastics market is affected by the stakeholders involved owing to their role in production processes, environmental guidelines and purchasing decisio...
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Growing population and expanding economies are important causes of increasing global energy demand. In wake of the continuous hike in the petroleum prices, depleting world resources and increased constant threat to planet's environment, the need for environment friendly alternative fuels has augmented many times. Metha...
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The present study uses cradle-to-factory gate life cycle assessment (LCA) to evaluate environmental impact categories in producing packaged canola edible oil in Isfahan province of Iran. In this study, LCA methodology is applied in order to satisfy two goals, namely, to evaluate hot spots in production chain of canola ...
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The operational stability, power efficiency, and technical simplicity of enzymatic biofuel cells are the focus area of research for practical applications of this green energy-generating device. Here, we report some critical findings on these issues on a methanol-fuelled pure biofuel cell fabricated by using alcohol ox...
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This chapter explores the processes of a typical logistics network for the management of reusable packaging for food products. While the impacts associated with packaging waste in the food sector are well known, the adoption of reusable crates or handling systems for food items entails many logistics processes such as ...
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The environmental performance of hemp based natural fiber mat thermoplastic (NMT) has been evaluated in this study by quantifying carbon storage potential and CO2 emissions and comparing the results with commercially available glass fiber composites. Non-woven mats of hemp fiber and polypropylene matrix were used to ma...
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Phospholipids are important biomolecules for the study of lipidomics, signal transduction, biodiesel, and synthetic biology; however, it is difficult to synthesize and analyze phospholipids in a defined in vitro condition. Here, we present a protocol for in vitro production and quantification of phospholipids. We descr...
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The energy-water nexus is a concept widely established but rarely applied to product and, in particular, to food and beverage products, which have a great influence on greenhouse gases emissions. The proposed method considers the main nexus aspects in addition to other relevant aspects such as climate change, which is ...
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Milk packaging has been analysed multiple times in pursuit of finding the most appropriate vessel from an environmental point of view. Research has concentrated on commercially available containers of 0.5 – 2.5 litres, usually made from High-Density Polyethylene (HDPE), Polyethylene Terephtalate (PET), paper-based cart...
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Consumption of plastic is steadily increasing, making disposal through landfilling, incineration, and open-or closed-loop recycling challenging. The majority of these plastic waste is Polyethylene Terephthalate (PET) bottles, widely used for single-use beverage and liquid containers. This study focuses on using Recycle...
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Methanol is a basic form of alcohol that results from the combination of a methyl group (CH3) and a hydroxy group (OH). The global demand for methanol is expected to reach 117Mtons in coming years owing to its mass use in the petrochemical, transportation, and chemical industries. Methanol is primarily synthesized usin...
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Synthesis of nanoparticles through the green approach using plant and vegetable extracts has gained popularity since they are thought to be efficient and cost-effective materials. This study is designed to synthesize zinc oxide nanoparticles (ZnO-NPs) from onion waste peel extract (Allium cepa L.) via the green synthes...
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The market growth of consumer electronics makes it essential for industries and policy-makers to work together to develop sustainable products. The objective of this study is to better understand how to promote environmentally sustainable consumer electronics by examining the use of various materials in laptop enclosur...
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Platinum supported on high surface area tungsten trioxide (WO3) has received intensive attention in recent years, mainly because of its improved tolerance towards carbon monoxide (CO) poisoning during methanol oxidation and its enhanced electrocatalytic activity. However, the chemical instability of WO3 in acid medium ...
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Plastic debris into the environment is a growing threat for the ecosystems and human health. The seafood sector is particularly concerned because it generates plastic losses and can be endangered by plastic contamination. Life cycle assessment (LCA) does not properly consider plastic losses and related impacts, which i...
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Petrochemical-based synthetic plastics poses a threat to humans, wildlife, marine life and the environment. Given the magnitude of eventual depletion of petrochemical sources and global environmental pollution caused by the manufacturing of synthetic plastics such as polyethylene (PET) and polypropylene (PP), it is ess...
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A structure's sustainability depends not only on its components, but also on the manufacturing process. The adhesive layer mostly increases the structural weight, reducing weight-specific properties, beside hindering its disassembly and sorting at end-of-life. This study investigates an alternative joining method based...
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The rapid growth of employing single-use plastic delivery bags (SPDBs) as express delivery packaging has led to serious resource depletion and environmental pollution. To mitigate these environmental threats, reusable plastic delivery boxes (RPDBs) were developed as an alternative option. This study utilized the life c...
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The consumption stage has been identified as the largest producer of food waste (FW) across the food supply chain (FSC), with fruit and vegetables being the most affected product category. The present study aims to determine the optimal storage scenario at household level to avoid food waste and which has the lowest en...
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A large number of polyethylene terephthalate (PET) bottles are discarded daily after usage. Thus, plastic bottle recycling has elicited considerable attention in recent years. In this context, this study aims to quantify the environmental and economic impacts of blanket production from 100% recycled waste plastic bottl...
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Green economic development has become a new strategy for large countries to contend with the energy crises and environmental pollution. Bamboo is a kind of sustainable resource with a fast growth rate and strong carbon fixation capacity which can be used to make various eco-friendly products. Bamboo fiber (BF) tablewar...
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This study presents a new, facile and fast strategy to synthesize platinum nanoparticles (Pt NPs) in methanol under ultrasonic irradiation. Here, for the first time, methanol was used to reduce Pt2+ to Pt0 in the absence of a reductive and surfactant. The hydroxyl free radical (OH•) liberated from methanol under the so...
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With the rapid and prosperous development of China's express delivery industry, the environmental issue of packaging waste has become increasingly pressing. Express packaging is diversified and complicated, with obstacles of excessive packaging and low recycling rate, which pose challenges to the low-carbon development...
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The direct synthesis of dimethyl ether (DME) from synthesis gas via methanol as an intermediate is a promising process for realizing a decentralized, small-scale Power-to-X concept. The efficient realization of this coupled process depends to a large extent on the appropriate catalyst configuration, i.e. the combinatio...
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Silver (Ag) and gold (Au) nanoparticles, have gained attention for their unique properties and diverse applications, including medicine and antimicrobial agents. To meet the demand for eco-friendly synthesis methods, we explored plant-mediated nanoparticle synthesis using Anemopsis californica extracts. The Anemopsis c...
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With increasing demand for the treatment of microbial resistance around the globe, it is necessary to develop metallic nanoparticles , ideally by the use of nontoxic medium i.e. plant constituents, that could arrest the microbial growth. For this reason, small and highly crystalline PdNPs were effectively synthesized b...
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Life Cycle Assessment (LCA) is nowadays one of the most applied methodologies for evaluating the potential environmental impacts of products and systems related to the plastic packaging sector. Nevertheless, the recent increasing interest on Circular Economy principles introduces challenges in its application, addressi...
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As a necessary component of traffic signal and the safety features on traffic system, pavement markings could not be replaced by other means currently. With the enhancement of environmental and healthy requirements, it was also crucial to reduce energy consumption and negative environmental impact of marking materials....
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With the introduction of Ga3+ into Cu/ZnO catalyst precursors, a series of catalysts have been prepared using a simple co-precipitation method and tested as catalysts for the synthesis of methanol from CO2 hydrogenation. It is found that the presence of a small amount of Ga3+ can facilitate thermal deep reduction of Zn...
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In this study, the size-selected platinum (Pt) nanoparticles are loaded on sulfonated graphene with polyvinyl alcohol (PVA) as the conductive polymer for fuel-cell applications. Methanol oxidation reactions and reliability of various catalysts based on carbon black, graphene, and sulfonated graphene catalyst supports a...
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The high efficiency of 2-cyanopyridine (2-CP) as dehydrating agent in the direct dimethyl carbonate (DMC) synthesis from CO2 and methanol over CeO2 catalysts has been recently demonstrated with excellent DMC yields (>90%) in both batch and continuous operations. The catalytic reaction is expected to involve a complex t...
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The global plastic sector urgently needs a circular economy and decarbonization since excessive plastic use is aggravating plastic pollution and climate change. In this regard, a novel strategy was proposed to close both the plastic loop and carbon loop using carbon capture, utilization, and storage (CCUS), which invol...
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The use of functional fillers added to PLA-based products can be beneficial in terms of cost reduction and properties improvement. The existing life cycle assessment of PLA containers mainly focuses on the greenhouse gas (GHG) emission of PLA material model without fillers, and overlooked environmental impacts of funct...
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The increasing amount of post-consumer plastic waste (PCPW) is a global concern. Well-established recycling technologies operate close to their limits. Innovative technologies like chemical recycling with uncertain environmental performance are developed. To anticipate unforeseen and unwanted consequences it is importa...
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As of yet, disposal platforms for synthetic polymers have not matured in an environmentally benign manner. Consequently, their wastes tend to remain as sources of pollution that chronically release hazardous substances. In a strategical sense, biopolymers synthesized from natural (plant/animal or microbial) sources are...
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Packaging can play a substantial role in moving towards more sustainable food systems by affecting the amount of food loss and waste. However, the use of plastic packaging gives rise to environmental concerns, such as high energy and fossil resource use, and waste management issues such as marine litter. Alternative bi...
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The use of single-atom catalysts (SACs) has emerged as a very promising advancement in the field of oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR). This is primarily attributed to their exceptional electrical properties and atomic efficiency. Nevertheless, the progress of electrocatalysis in the ...
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Most plastics are today mechanically recycled (MR), whereas chemical recycling (CR) is an emerging technology. Substitutability of virgin material is vital for their environmental performance assessed through life cycle assessment (LCA). MR faces the reduction in the material’s technical quality but also the potential ...
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Plastic pollution of the natural environment world-wide is ubiquitous. More than 80% of marine litter is made of plastics, 70% of which originates from disposable items, so plastic disposables need to be replaced with disposables made from renewable materials. However, it is important to investigate the environmental i...
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Although plastics emissions pose hazards to ecosystem quality, life cycle assessment (LCA) methodologies do not yet include quantification of the potential impacts of plastic leakage. To address this gap in LCA, the MarILCA working group was founded. This work contributes to MarILCA's output by providing characterizati...
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Methanol is a recognized renewable clean energy. In the context of carbon neutrality, it is of great significance to achieve low-carbon production of methanol fuel and its application in internal combustion (IC) engines to reduce emissions. First, this article systematically introduced and evaluated the technical route...
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In this work, a detailed thermodynamic analysis and simulation of an intensified process for CO2 hydrogenation to methanol with in-situ water sorption is presented. The study focused on the effect of different operating parameters, such as temperature, pressure, H2/CO2 molar ratio and adsorbent volume capacity, on the ...
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Currently, Belgium is in a transition period after which more household plastic packaging waste will be collected separately in function of increased recycling. The challenge is to identify the most environmentally sound treatment option for the increased selectively collected plastic waste. In this study, mechanical r...
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The plastic industry is a high carbon emission industry in China. Previous studies mainly focused on the flows and stocks of polystyrene (PS), polyvinyl chloride (PVC), and acrylonitrile-butadiene-styrene (ABS) plastics. However, there is limited detailed information on the GHG emissions of PS, PVC, and ABS in China an...
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The major hurdle in recovering from the COVID-19 pandemic would be the safe management of plastic waste generated from personal protective equipment and mitigating a plastic pollution crisis. Facemasks were adopted worldwide as the first line of defense against the COVID-19 pandemic, and their demand increased exponent...
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Herein, reduced graphene oxide supported well-dispersed bimetallic AuPt alloy nanodendrites (AuPt ANDs/rGO) were fabricated by a one-pot coreduction approach using ionic liquid (1-aminopropyl-3-methylimidazolium bromide, [APMIm]Br) as the stabilizer and capping agent. There is no any other polymer or seed involved. Cha...
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The discovery of low cost and efficient catalytic materials for the oxygen reduction reaction (ORR) is of paramount importance for industrial-scale fuel cell manufacture. In this work, a convenient and straightforward approach was designed and applied to produce iron and nitrogen co-doped biomass carbon/graphene compos...
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Plastic mulching film (PMF) enhances grain yields, while leading to negative effects on water depletion, environmental impact, and plastic residues if not properly controlled. By constructing a Food–Water–Environment–Plastic nexus effect analysis model jointly utilizing the WOFOST model, mixed regression, and life cycl...
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A comparative life cycle assessment analysis among pressure bag molding and bag molding with autoclave for the manufacturing of car components in carbon fiber reinforced plastic (CFRP) was carried out. Four scenarios were analyzed: i) autoclave bag molding with aluminum mold, ii) autoclave bag molding with CFRP mold an...
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The styrene oxide to styrene carbonate conversion performed in CO2 atmosphere, herein selected as a case study, was implemented in microdroplets (aerosol) reactions at the preparative scale (3.5 mmol of the starting material) and mild conditions (1 atm CO2 pressure), within a custom-made ultrasonic nebulization reactor...
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Sustainable Development Goals (SDG) 12: Responsible consumption and production and 14: Life Below Water coincide in the targeting of the problem of plastic pollution. The problem has been garnering immense media attention in the recent years. Efforts to reduce unnecessary plastic consumption have been seen in social mo...
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Bimetallic PtPd nanocubes supported on graphene nanosheets (PtPdNCs/GNs) were prepared by a rapid, one-pot and surfactant-free method, in which N,N-dimethylformamide (DMF) was used as a bi-functional solvent for the reduction of both metal precursors and graphene oxide (GO) and for the surface confining growth of PtPdN...
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The production and pollution of plastic present a significant threat to global ecosystems, where annual plastic emissions in aquatic ecosystems are projected to triple between 2020 and 2030. Currently, plastics are widely used for food packaging but depending on the polymers, properties, the recyclability ratio of the ...
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The phytochemical, antioxidants and antimicrobial potential of aqueous and methanol fruit extracts of Nauclea latifolia (African peach) and its application in biosynthesis of silver nanoparticles and its cold cream formulations were investigated. The phytochemical constituents, antioxidant and antimicrobial potential o...
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The climate crisis calls for a shift from petrochemicals to bio-based products to reduce environmental consequences. Polylactic acid (PLA) is one of the most widely used biopolymers, due to its mechanical properties and renewable origin, to produce bio-based compostable plastic for food packaging. The objective of this...
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One of the key challenges for plastics in a circular economy is its degradation during use, washing and reprocessing. The reduced quality of recycled plastic waste leads to its use in inferior applications. This study presents a novel quality model which incorporates degradation, degree of mixing and contaminations. Th...
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A series of Cu/CNT catalysts were applied for CO2 hydrogenation to methanol in three phase reactor. In order to probe the promotion role of copper, catalysts with 0.2, 0.4, and 0.8 wt. % of Cu were synthesized by precipitation method. Different analytical techniques like Inductively Coupled Plasma-Optical Emission Spec...
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The environmental impact of packaging has already been studied since the early development of the life cycle assessment (LCA) methodology, and today an extensive amount of studies exists. LCAs inform policy makers and guide companies in developing more environmentally sustainable packaging. From both a policy and a bus...
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Plastic pollution is a pressing global concern due to its severe environmental impacts. Thus, the adoption of sustainable practices in product design and end-of-life management has become paramount towards a plastic's circular economy. This study delves into the transformative potential of design for recycling by exami...
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The distribution of liquid detergents through self-dispensing systems has been adopted in some Italian retail stores over the last few years. By enabling the consumer to refill several times the same container, it is proposed as a less waste-generating and more environmentally friendly alternative to the traditional di...
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The performance of ZSM-5, γ-Al2O3 and WO3/SiO2 catalysts for the dehydration of methanol was studied in a fixed bed reactor over a temperature range of 150 to 450 °C and at atmospheric pressure. A parallel reaction scheme for dehydration of methanol to dimethyl ether and methane was proposed for the WO3/SiO2 catalyst, ...
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Although the high efficiency of the homogeneous processes, using rhodium or iridium complexes, was clearly demonstrated industrially, heterogeneous catalysts offer the advantages of facile product separation and vapor phase operation, which often limit catalyst losses. Both noble and non-noble metal homogeneous and het...
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Using the synthesis method, we produced a series of 2‑hydroxy-4-benzyloxybenzylidene N- or S-alkyl chains substituted thiosemicarbazones and their dioxomolybdenum(VI) complexes containing long alkyl chains (pentyl, hexyl, heptyl, and octyl). A series of dioxomolybdenum(VI) complexes with 2‑hydroxy-4-benzyloxybenzyliden...
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Au@Pt core–shell nanoparticles were successfully synthesized by successive reduction of HAuCl4 and H2PtCl6 and were then assembled on Vulcan XC-72 carbon surface (noted as Au@Pt/C). The morphology and distribution of Au@Pt nanoparticles were characterized by UV–vis spectroscopy, transmission electron microscopy (TEM), ...
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SAPO-34 molecular sieves synthesized using calcined kaolin as partial raw material under three-stage of high-low-high temperature hydrothermal condition are explored systematically. Especially, the effect of kaolin calcination temperature on the crystallization mechanism of SAPO-34 and the methanol to olefin performanc...
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